منابع مشابه
Investigating hydration dependence of dynamics of confined water: monolayer, hydration water and Maxwell-Wagner processes.
The dynamics of water confined in silica matrices MCM-41 C10 and C18, with pore diameter of 21 and 36 A, respectively, is examined by broadband dielectric spectroscopy (10(-2)-10(9) Hz) and differential scanning calorimetry for a wide temperature interval (110-340 K). The dynamics from capillary condensed hydration water and surface monolayer of water are separated in the analysis. Contrary to ...
متن کاملHydration, hydration, hydration.
Throughout the world, large numbers of manual workers perform physically demanding labour in conditions of high environmental heat stress. Although the importance of adequate hydration in combating heat stress is universally recognized, studies in a range of worker groups have demonstrated a disturbingly poor hydration level in a high proportion of at-risk workers. Management of work in hot env...
متن کاملHydration of dimethyldodecylamine-N-oxide: enthalpy and entropy driven processes.
Dimethyldodecylamine-N-oxide (DDAO) has only one polar atom that is able to interact with water. Still, this surfactant shows very hydrophilic properties: in mixtures with water, it forms normal liquid crystalline phases and micelles. Moreover, there is data in the literature indicating that the hydration of this surfactant is driven by enthalpy while other studies show that hydration of surfac...
متن کاملThe impact of structural modification of 1,2,4-thiadiazole derivatives on thermodynamics of solubility and hydration processes.
The influence of a structural modification on thermodynamic aspects of solubility and hydration processes of 1,2,4-thiadiazole drug-like compounds was investigated. A substitution in the phenyl ring of the 1,2,4-thiadiazole molecule leads to a significant decrease of the solubility of these compounds. In order to rationalize the relationship between the structures of 1,2,4-thiadiazoles and thei...
متن کاملInitial hydration processes of magnesium chloride: size-selected anion photoelectron spectroscopy and ab initio calculations.
To understand the initial hydration processes of MgCl2, we measured photoelectron spectra of MgCl2(H2O)n- (n = 0-6) and conducted ab initio calculations on MgCl2(H2O)n- and their neutral counterparts up to n = 7. A dramatic drop in the vertical detachment energy (VDE) was observed upon addition of the first water molecule to bare MgCl2-. This large variation in VDE can be associated with the ch...
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ژورنال
عنوان ژورنال: Nature
سال: 1970
ISSN: 0028-0836,1476-4687
DOI: 10.1038/227312b0